Hexatic phase and water-like anomalies in a two-dimensional fluid of particles with a weakly softened core.
نویسندگان
چکیده
We study a two-dimensional fluid of particles interacting through a spherically symmetric and marginally soft two-body repulsion. This model can exist in three different crystal phases, one of them with square symmetry and the other two triangular. We show that, while the triangular solids first melt into a hexatic fluid, the square solid is directly transformed on heating into an isotropic fluid through a first-order transition, with no intermediate tetratic phase. In the low-pressure triangular and square crystals, melting is reentrant provided the temperature is not too low, but without the necessity of two competing nearest-neighbor distances over a range of pressures. A whole spectrum of water-like fluid anomalies completes the picture for this model potential.
منابع مشابه
Hexatic phase in the two-dimensional Gaussian-core model.
We present a Monte Carlo simulation study of the phase behavior of two-dimensional classical particles repelling each other through an isotropic Gaussian potential. As in the analogous three-dimensional case, a reentrant-melting transition occurs upon compression for not too high temperatures, along with a spectrum of waterlike anomalies in the fluid phase. However, in two dimensions melting is...
متن کاملTwo-dimensional melting under quenched disorder.
We study the influence of quenched disorder on the two-dimensional melting behavior of superparamagnetic colloidal particles, using both video microscopy and computer simulations of repulsive parallel dipoles. Quenched disorder is introduced by pinning a fraction of the particles to an underlying substrate. We confirm the occurrence of the Kosterlitz-Thouless-Halperin-Nelson-Young scenario and ...
متن کاملSelf-Assembly and Water-like Anomalies in Janus Nanoparticles.
We explore the pressure versus temperature phase diagram of a system of dimeric Janus nanoparticles using molecular dynamics simulations. Each nanoparticle is modeled as a dumbbell which has one monomer that interacts by a standard Lennard-Jones potential while the other monomer interacts by a core-softened potential. The systems composed by particles interacting only by core-softened potential...
متن کاملCore-softened fluids, water-like anomalies, and the liquid-liquid critical points.
Molecular dynamics simulations are used to examine the relationship between water-like anomalies and the liquid-liquid critical point in a family of model fluids with multi-Gaussian, core-softened pair interactions. The core-softened pair interactions have two length scales, such that the longer length scale associated with a shallow, attractive well is kept constant while the shorter length sc...
متن کاملThe Interpretation of Water Anomalies in Terms of Core-Softened Models
In the first part of this paper I review the understanding of anomalous properties of water in terms of particles interacting by core-softened potentials. I discuss the origin of the bulk anomalies in terms of the two different configurations of neighbor particles: low energy–high volume and high energy–low volume. In the second part I study some anomalies of water under strong spatial confinem...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- The Journal of chemical physics
دوره 137 10 شماره
صفحات -
تاریخ انتشار 2012